Simultaneous determination of chlorantraniliprole and cyantraniliprole in fruits, vegetables and cereals using ultra-high-performance liquid chromatography–tandem mass spectrometry with the isotope-labelled internal standard method

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• 作者：Xinglu Pan ; Fengshou Dong ; Jun Xu ; Xingang Liu…
• 关键词：Isotope ; labelled internal standard method ; Chlorantraniliprole ; Cyantraniliprole ; Ultra ; high ; performance liquid chromatography–tandem mass spectrometry ; Quick ; Easy ; Cheap ; Effective ; Rugged and safe
• 刊名：Analytical and Bioanalytical Chemistry
• 出版年：2015
• 出版时间：May 2015
• 年：2015
• 卷：407
• 期：14
• 页码：4111-4120
• 全文大小：1,174 KB
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• 作者单位：Xinglu Pan (1)
  Fengshou Dong (1)
  Jun Xu (1)
  Xingang Liu (1)
  Zenglong Chen (1)
  Na Liu (1) (2)
  Xixi Chen (1)
  Yan Tao (1)
  Hongjun Zhang (3)
  Yongquan Zheng (1)
  
  1. State Key Laboratory for Biology of Plant Disease and Insect Pests, Institute of Plant Protection, Chinese Academy of Agricultural Sciences, No. 2 Yuanmingyuan West Road, Haidian District, Beijing, 100193, China
  2. College of Plant Protection, Shenyang Agricultural University, No.120 Dongling Road, Shenyang, Liaoning, 110866, China
  3. Institute for the Control of Agrochemicals, Ministry of Agriculture, No. 9 North third ring road, Haidian District, Beijing, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Analytical Chemistry
  Food Science
  Inorganic Chemistry
  Physical Chemistry
  Monitoring, Environmental Analysis and Environmental Ecotoxicology
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1618-2650

文摘

A reliable and sensitive isotope-labelled internal standard method for simultaneous determination of chlorantraniliprole and cyantraniliprole in fruits (apple and grape), vegetables (cucumber and tomato) and cereals (rice and wheat) using ultra-high-performance liquid chromatography–tandem mass spectrometry was developed. Isotope-labelled internal standards were effective in compensating for the loss in the pretreatment and overcoming the matrix effect. The analytes were extracted with acetonitrile and cleaned up with different kinds of sorbents. The determination of the target compounds was achieved in less than 4?min using a T3 column combined with an electrospray ionization source in positive mode. The overall average relative recoveries in all matrices at three spiking levels (10, 20 and 50?μg?kg-1) ranged from 95.5 to 106.2?%, with all relative standard deviations being less than 14.4?% for all analytes. The limits of detection did not exceed 0.085?μg?kg-1 and the limits of quantification were below 0.28?μg?kg-1 in all matrices. The method was demonstrated to be convenient and accurate for the routine monitoring of chlorantraniliprole and cyantraniliprole in fruits, vegetables and cereals.