2-Iodylphenol Ethers: Preparation, X-ray Crystal Structure, and Reactivity of New Hypervalent Iodine(V) Oxidizing Reagents

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• 作者：Alexey Y. Koposov ; Rashad R. Karimov ; Ivan M. Geraskin ; Victor N. Nemykin ; Viktor V. Zhdankin
• 刊名：Journal of Organic Chemistry
• 出版年：2006
• 出版时间：October 27, 2006
• 年：2006
• 卷：71
• 期：22
• 页码：8452 - 8458
• 全文大小：290K
• 年卷期：v.71,no.22(October 27, 2006)
• ISSN：1520-6904

文摘

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2-Iodylphenol ethers were prepared by the dimethyldioxirane oxidation of the corresponding 2-iodophenolethers and isolated as chemically stable, microcrystalline products. Single-crystal X-ray diffraction analysisof 1-iodyl-2-isopropoxybenzene 8c and 1-iodyl-2-butoxybenzene 8d revealed pseudopolymeric arrangements in the solid state formed by intermolecular interactions between IO₂ groups of different molecules.2-Iodylphenol ethers can selectively oxidize sulfides to sulfoxides and alcohols to the respective aldehydesor ketones.