Organoiodine(V) Reagents in Organic Synthesis

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• 作者：Viktor V. Zhdankin
• 刊名：Journal of Organic Chemistry
• 出版年：2011
• 出版时间：March 4, 2011
• 年：2011
• 卷：76
• 期：5
• 页码：1185-1197
• 全文大小：1444K
• 年卷期：v.76,no.5(March 4, 2011)
• ISSN：1520-6904

文摘

Organohypervalent iodine reagents have attracted significant recent interest as versatile and environmentally benign oxidants with numerous applications in organic synthesis. This Perspective summarizes synthetic applications of hypervalent iodine(V) reagents: 2-iodoxybenzoic acid (IBX), Dess鈭扢artin periodinane (DMP), pseudocyclic iodylarenes, and their recyclable polymer-supported analogues. Recent advances in the development of new catalytic systems based on the generation of hypervalent iodine species in situ are also overviewed.