Novel Metallacycle Complexes from Bis(oxazolinyl)pyridine-Rhodium(I) Species and Diynes

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• 作者：Hisao Nishiyama ; Eiko Niwa ; Tomohiro Inoue ; Yosuke Ishima ; and Katsuyuki Aoki
• 刊名：Organometallics
• 出版年：2002
• 出版时间：June 24, 2002
• 年：2002
• 卷：21
• 期：13
• 页码：2572 - 2574
• 全文大小：64K
• 年卷期：v.21,no.13(June 24, 2002)
• ISSN：1520-6041

文摘

The reaction of [Rh(coe)₂Cl]₂ (coe = cis-cyclooctene), bis(oxazolinyl)pyridine (pybox), and diynes(O(CH₂CCCO₂Me)₂ and PhCCCH₂OCH₂CCCO₂Me) gave new types of metallacycle complexes, whichwere analyzed by X-ray crystallography and showedcatalytic activity for cycloaddition of diynes and severalalkynes.