Synthesis of Micro-Mesoporous Composites MCM-41/13X and Their Application on CO2 Adsorption: Experiment and Modeling

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• 作者：Changchun Ji ; Li Zhang ; Lei Li ; Feng Li ; Fukui Xiao ; Ning Zhao ; Wei Wei ; Yanjun Chen ; Feng Wu
• 刊名：Industrial & Engineering Chemistry Research
• 出版年：2016
• 出版时间：July 27, 2016
• 年：2016
• 卷：55
• 期：29
• 页码：7853-7859
• 全文大小：447K
• 年卷期：0
• ISSN：1520-5045

文摘

Two micromesoporous composites of MCM-41/13X are synthesized through a two-step crystallization process and a one-step crystallization process, respectively. The results of X-ray diffraction, nitrogen adsorption–desorption isotherms, Fourier transform infrared spectroscopy, and transmission electron microscopy results show that the as-prepared samples possessed both micropores and mesopores. The materials take advantage of not only the large adsorption capacity and thermal stability of the microporous material, but also the rapid diffusion and mass transfer of mesoporous materials, which lead to improve CO₂ adsorption capacities compared to the pure microporous or mesoporous materials.