Bis(dipyrrinato)zinc(II) Complexes: Emission in the Solid State

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• 作者：Mizuho Tsuchiya ; Ryota Sakamoto ; Masaki Shimada ; Yoshinori Yamanoi ; Yohei Hattori ; Kunihisa Sugimoto ; Eiji Nishibori ; Hiroshi Nishihara
• 刊名：Inorganic Chemistry
• 出版年：2016
• 出版时间：June 20, 2016
• 年：2016
• 卷：55
• 期：12
• 页码：5732-5734
• 全文大小：263K
• 年卷期：0
• ISSN：1520-510X

文摘

This Communication reports the first observation of solid-state photoluminescence in bis(dipyrrinato)zinc(II) complexes with various substituents. The report discusses the effect of their substituents on their crystal structures and spectroscopic properties. Their meso-aryl groups are revealed to play important roles in the spectroscopic properties in the solid state.