Pentacoordinate Organoantimony Compounds That Isomerize by Turnstile Rotation

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• 作者：Shiro Matsukawa^† ; ; Hideaki Yamamichi^† ; ; Yohsuke Yamamoto*^† ; ; Kaori Ando^‡ ;
• 刊名：Journal of the American Chemical Society
• 出版年：2009
• 出版时间：March 18, 2009
• 年：2009
• 卷：131
• 期：10
• 页码：3418-3419
• 全文大小：140K
• 年卷期：v.131,no.10(March 18, 2009)
• ISSN：1520-5126

文摘

Two stereoisomers of pentacoordinate antimony compounds (stiboranes) with a new rigid tridentate ligand were synthesized, and the isomerization was found to proceed by the turnstile rotation (TR) mechanism with the tridentate ligand as a trio and the two monodentate ligands as a pair.