One-Step Preparation of Oxygen/Fluorine Dual Functional MWCNTs with Good Water Dispersibility by the Initiation of Fluorine Gas

详细信息    查看全文

• 作者：Yang Liu ; Xu Wang ; Weimiao Wang ; Baoyin Li ; Peng Wu ; Mengmeng Ren ; Zheng Cheng ; Teng Chen ; Xiangyang Liu
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2016
• 出版时间：March 30, 2016
• 年：2016
• 卷：8
• 期：12
• 页码：7991-7999
• 全文大小：619K
• ISSN：1944-8252

文摘

It is still a challenge to prepare water-dispersible carbon nanotubes which are proved to have great potential in numerous applications. In this present work, as low as 2% fluorine gas was used as initiator to prepare oxygen/fluorine dual functional MWCNTs (OF-MWCNTs) with good water dispersibility through a one-step method under oxygen atmosphere. The aromatic structure of OF-MWCNTs is reserved to some extent resulting in better electrical conductivity than pure fluorinated MWCNTs (F-MWCNTs). The amount of oxygen atoms and fluorine atoms (hereinafter referred to as “O-content” and “F-content”) of OF-MWCNTs is up to 8.8% and 7.5%. Fourier transform infrared spectroscopy (FTIR) manifests that - COOH is covalently bonded onto the surface of OF-MWCNTs. In addition, the OF-MWCNTs sample is pH-sensitive, which further validates the successful introduction of -COOH. The successful covalent attachment of -COOH onto MWCNTs dramatically improves the hydrophilia of MWCNTs which always present hydrophobic character. It is deduced that fluorine creates reactive sites for oxygen, increases the oxygen content, and eventually results in the dispersibility of OF-MWCNTs in water. The corresponding hydrophilic OF-MWCNTs film shows good performance for separating oil-in-water emulsions. Meanwhile, the good dispersibility of OF-MWCNTs in organic solvents also makes it possible to be applied in various composites.