Pd-Catalyzed Regiodivergent Hydroesterification of Aryl Olefins with Phenyl Formate

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• 作者：Wenlong Ren ; Wenju Chang ; Yang Wang ; Jingfu Li ; Yian Shi
• 刊名：Organic Letters
• 出版年：2015
• 出版时间：July 17, 2015
• 年：2015
• 卷：17
• 期：14
• 页码：3544-3547
• 全文大小：398K
• ISSN：1523-7052

文摘

An effective Pd-catalyzed regiodivergent hydroesterification of aryl olefins with phenyl formate is described. Either linear or branched phenyl arylpropanoates can be obtained in good yields with high regioselectivities by the judicious choice of ligand without the use of toxic CO gas.