Studies on Polymorphic Sequence during the Formation of the 1:1 Ordered Perovskite-Type BaCa0.335M0.165Nb0.5O3-未 (M = Mn, Fe, Co) Using in Situ and ex Situ

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• 作者：Wang Hay Kan ; Joey Lussier ; Mario Bieringer ; Venkataraman Thangadurai
• 刊名：Inorganic Chemistry
• 出版年：2014
• 出版时间：October 6, 2014
• 年：2014
• 卷：53
• 期：19
• 页码：10085-10093
• 全文大小：840K
• ISSN：1520-510X

文摘

Here, we report a synthetic strategy to control the B-site ordering of the transition metal-doped perovskite-type oxides with the nominal formula of BaCa_0.335M_0.165Nb_0.5O_3-未 (M = Mn, Fe, Co). Variable temperature (in situ) and ex situ powder X-ray diffraction (PXRD), selected area electron diffraction (SAED), energy dispersive X-ray spectroscopy (EDX), Fourier transform infrared spectroscopy (FTIR), scanning/transmission electron microscopy (SEM/TEM), and thermogravimetic analysis (TGA) were used to understand the B-site ordering as a function of temperature. The present study shows that BaCa_0.335M_0.165Nb_0.5O_3-未 crystallizes in the B-site disordered primitive perovskite (space group s.g. Pm3虆m) at 900 掳C in air, which can be converted into the B-site 1:2 ordered perovskite (s.g. P3虆m1) at 1200 掳C and the B-site 1:1 ordered perovskite phase (s.g. Fm3虆m) at 1300 掳C. However, the reverse reaction is not feasible when the temperature is reduced. FTIR revealed that no carbonate species were present in all three polymorphs. The chemical stability of the investigated perovskites in CO₂ and H₂ highly depends on the B-site cation ordering. For example, TGA confirmed that the B-site disordered primitive perovskite phase is more readily reduced in dry and wet 10% H₂/90% N₂ and is less stable in pure CO₂ at elevated temperature, compared to the B-site 1:1 ordered perovskite-type phase of the same nominal composition.