Methano[10]annulene Revisited: Extended Delocalization through Conjugated Polymers Bearing Larger Hückel Aromatics
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- 作者：Patricia A. Peart ; John D. Tovar
- 刊名：Organic Letters
- 出版年：2007
- 出版时间：August 2, 2007
- 年：2007
- 卷：9
- 期：16
- 页码：3041 - 3044
- 全文大小：98K
- 年卷期：v.9,no.16(August 2, 2007)
- ISSN：1523-7052
文摘
electron circuits of naphthalene and methano[10]annulene is presented.The annulene topology allows for a greater degree of intrapolymer charge delocalization, a key structural parameter for enhancing theperformance of organic semiconductors. Molecular design and synthesis based upon unusual aromatic cores will enable facile transportproperties that would not ordinarily be realized under the 6 electron aromatic paradigm.