Synergistic Toughening of Epoxy Modified by Graphene and Block Copolymer Micelles

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• 作者：Tuoqi LiSiyao He ; Andreas Stein ; Lorraine F. Francis ; Frank S. Bates
• 刊名：Macromolecules
• 出版年：2016
• 出版时间：December 27, 2016
• 年：2016
• 卷：49
• 期：24
• 页码：9507-9520
• 全文大小：804K
• ISSN：1520-5835

文摘

Binary composites formed by individually mixing exfoliated graphene oxide modified with amine-terminated poly(butadiene–acrylonitrile) (GA) and a spherical micelle forming poly(ethylene oxide)-b-poly(ethylene-alt-propylene) (OP) diblock copolymer with a thermoset epoxy, and the associated GA/OP/epoxy ternary composites, were prepared and studied as a function of the molecular weight M_c between cross-links. The rigid GA filler dispersed well in the cured epoxies as established by transmission electron microscopy (TEM). The toughening efficacy of GA alone was found to depend strongly on the modifier concentration and the matrix cross-link density with an optimal 1.7-fold increase in the critical strain energy release rate (G_Ic) over the neat epoxy obtained with a 0.04 wt % loading in the most lightly cross-linked (M_c = 6100 g/mol) material. Addition of 5 wt % OP to this epoxy resin enhanced G_Ic by a factor of 12. Combining the hard GA and soft OP modifiers at the same loading levels (0.04 and 5 wt %, respectively) resulted in 18 times the G_Ic of the unmodified material, a 31% improvement over the effect anticipated by simple addition of the fracture properties of the binary composites. Decreasing M_c to 700 g/mol eliminated this synergistic effect while reducing the overall improvement in G_Ic to just 3 times that of the neat epoxy. Topological features on the fracture surfaces, imaged using a scanning electron microscope (SEM), suggest that the synergistic toughening of the GA/OP/epoxy ternary composite involves concurrent mechanisms operating on different length scales, including micelle cavitation and graphene debonding, resulting in simultaneous shear yielding, crack pinning, and crack deflection.