Investigating Reaction Conditions To Control the Self-Assembly of Cobalt-Seamed Nanocapsules

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• 作者：Asanka S. Rathnayake ; Kyle A. Feaster ; Joshua White ; Charles L. Barnes ; Simon J. Teat ; Jerry L. Atwood
• 刊名：Crystal Growth & Design
• 出版年：2016
• 出版时间：July 6, 2016
• 年：2016
• 卷：16
• 期：7
• 页码：3562-3564
• 全文大小：281K
• 年卷期：0
• ISSN：1528-7505

文摘

The synthesis and X-ray crystallographic structure of the first cobalt-seamed hexameric nanocapsule, [Co₂₄(C-pentylpyrogallol[4]arene)₆], is presented. The overall metal–ligand arrangement of this novel capsule is similar to that of previously reported copper- and nickel-seamed hexameric nanocapsules. However, the title nanocapsule encloses a larger void space than those found in previous hexameric nanocapsules.