Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method

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• 作者：Hongping Wu ; Hongwei Yu ; Qiang Bian ; Zhihua Yang ; Shujuan Han ; Shilie Pan
• 刊名：Inorganic Chemistry
• 出版年：2014
• 出版时间：December 15, 2014
• 年：2014
• 卷：53
• 期：24
• 页码：12686-12688
• 全文大小：235K
• ISSN：1520-510X

文摘

By incorporation of the largest-electronegativity F atoms into borate, two novel halogen-containing borates, Li₆RbB₂O₆F and K₃B₃O₃F₆, have been synthesized. Interestingly, Li₆RbB₂O₆F is the first borate fluoride in alkali-metal borate. Meanwhile, K₃B₃O₃F₆ appears to be the first confirmed alkali-metal fluoroborate crystal grown by a high-temperature solution in air.