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How Copper Nanowires Grow and How To Control Their Properties
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  • 作者:Shengrong Ye ; Ian E. Stewart ; Zuofeng Chen ; Bo Li ; Aaron R. Rathmell ; Benjamin J. Wiley
  • 刊名:Accounts of Chemical Research
  • 出版年:2016
  • 出版时间:March 15, 2016
  • 年:2016
  • 卷:49
  • 期:3
  • 页码:442-451
  • 全文大小:711K
  • 年卷期:Shengrong Ye
    (1979) received his Ph.D. from West Virginia University in 2011 and is currently a postdoctoral researcher with Prof. Benjamin J. Wiley at Duke University. His research interests center on the mechanistic investigation of metal nanowires to improve the control over their dimensions and properties.

    Ian E. Stewart
    (1990) is currently pursuing a Ph.D. in Chemistry at Duke University under the guidance of Prof. Benjamin J. Wiley. His research centers on improving the properties of CuNW electrodes and exploring their incorporation into various thin film applications.

    Zuofeng Chen
    (1979) received his Ph.D. with Prof. Vivian Wing-Wah Yam and Dr. Yanbing Zu at the University of Hong Kong in 2009. He then became a postdoctoral researcher with Profs. Thomas J. Meyer at the University of North Carolina—Chapel Hill (2009–2013) and Benjamin J. Wiley at Duke University (2013–2014). He is currently a Professor in the Department of Chemistry at Tongji University. His research interests include the development of transparent electrodes and catalysts for solar fuel production.

    Bo Li
    (1987) is currently pursuing a Ph.D. in Materials Science and Engineering at Donghua University under the guidance of Prof. Junqing Hu. In 2014, he joined the laboratory of Prof. Benjamin J. Wiley as a joint training Ph.D. Bo focuses on the structure–property relationships of metal nanowires for photovoltaic application.

    Aaron R. Rathmell
    (1985) received his Ph.D. in Chemistry from Duke University under the direction of Prof. Benjamin J. Wiley in 2013. Currently Aaron is a principal scientist at Physical Sciences Inc. in Andover, MA. His research interests center on the synthesis of various metal nanostructures and their incorporation into new and exciting devices.

    Benjamin J. Wiley
    (1981) is an Assistant Professor in the Department of Chemistry at Duke University. He received his Ph.D. in Chemical Engineering from the University of Washington in 2007, working on the synthesis of silver nanostructures under the guidance of Prof. Younan Xia. Prior to joining Duke in 2009, he was a postdoctoral fellow in the laboratory of Prof. George Whitesides at Harvard University. His lab focuses on the processes by which atoms assemble to form nanostructures in solution and the relationship between the structure and properties of these nanostructures in the context of practical applications.
  • ISSN:1520-4898
文摘
Scalable, solution-phase nanostructure synthesis has the promise to produce a wide variety of nanomaterials with novel properties at a cost that is low enough for these materials to be used to solve problems. For example, solution-synthesized metal nanowires are now being used to make low cost, flexible transparent electrodes in touch screens, organic light-emitting diodes (OLEDs), and solar cells. There has been a tremendous increase in the number of solution-phase syntheses that enable control over the assembly of atoms into nanowires in the last 15 years, but proposed mechanisms for nanowire formation are usually qualitative, and for many syntheses there is little consensus as to how nanowires form. It is often not clear what species is adding to a nanowire growing in solution or what mechanistic step limits its rate of growth. A deeper understanding of nanowire growth is important for efficiently directing the development of nanowire synthesis toward producing a wide variety of nanostructure morphologies for structure–property studies or producing precisely defined nanostructures for a specific application.

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