A Novel Diruthenium Acetylide Donor Complex as an Unusual Active Material for Bulk Heterojunction Solar Cells

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• 作者：Alessia Colombo ; Claudia Dragonetti ; Dominique Roberto ; Renato Ugo ; Luigi Falciola ; Silvia Luzzati ; Dariusz Kotowski
• 刊名：Organometallics
• 出版年：2011
• 出版时间：March 28, 2011
• 年：2011
• 卷：30
• 期：6
• 页码：1279-1282
• 全文大小：745K
• 年卷期：v.30,no.6(March 28, 2011)
• ISSN：1520-6041

文摘

A new dinuclear Ru(II) complex where two Ru atoms are separated by a bridge consisting of a 2,1,3-benzothiadiazole acceptor moiety flanked on either side by 2,5-thienyl donor units was synthesized. This rather simple complex appears to behave as a photoactive donor when blended with a fullerene as acceptor, thus being a first step toward novel bulk heterojunction solar cells, based on Ru donor systems.