Kinetically Controlled Assembly of a Spirocyclic Aromatic Hydrocarbon into Polyhedral Micro/Nanocrystals
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- 作者：Zong-Qiong Lin ; Peng-Ju Sun ; Yee-Yan Tay ; Jing Liang ; Yi Liu ; Nai-En Shi ; Ling-Hai Xie ; Ming-Dong Yi ; Yan Qian ; Qu-Li Fan ; Hua Zhang ; Huey Hoon Hng ; Jan Ma ; Qichun Zhang ; Wei Huang
- 刊名：ACS Nano
- 出版年：2012
- 出版时间：June 26, 2012
- 年：2012
- 卷：6
- 期：6
- 页码：5309-5319
- 全文大小：735K
- 年卷期：v.6,no.6(June 26, 2012)
- ISSN：1936-086X
文摘
Nonplane molecules with multiple large aromatic planes could be promising candidates to form various polyhedral micro/nanocrystals by manipulating the different 蟺路路路蟺 stacking, tuning the cohesive energies of crystal facets, and controlling the kinetic growth process. Spirocyclic aromatic hydrocarbons (SAHs) not only have two cross-shaped aromatic planes but also offer the feature of supramolecular steric hindrance, making it favorable for the heterogeneous kinetic growth into highly symmetric polyhedra. Herein, we report that a novel SAH compound, spiro[fluorene-9,7鈥?dibenzo[c,h]acridine]-5鈥?one (SFDBAO), can self-assemble into various monodispersed shapes such as hexahedra, octahedra, and decahedra through the variation of either different types of surfactants, such as Pluronic 123 (P123) and cetyltrimethyl ammonium bromide (CTAB), or growth parameters. In addition, the possible mechanism of crystal facet growth has been proposed according to the SEM, XRD, TEM, and SAED characterization of organic polyhedral micro/nanocrystals. The unique cruciform-shaped SAHs have been demonstrated as fascinating supramolecular synthons for various highly symmetric polyhedral assembling.