Graphene Oxides Dispersing and Hosting Graphene Sheets for Unique Nanocomposite Materials

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• 作者：Leilei Tian ; Parambath Anilkumar ; Li Cao ; Chang Yi Kong ; Mohammed J. Meziani ; Haijun Qian ; L. Monica Veca ; Tim J. Thorne ; Kenneth N. Tackett II ; Travis Edwards ; Ya-Ping Sun
• 刊名：ACS Nano
• 出版年：2011
• 出版时间：April 26, 2011
• 年：2011
• 卷：5
• 期：4
• 页码：3052-3058
• 全文大小：1389K
• 年卷期：0
• ISSN：1936-086X

文摘

Graphene oxides (GOs), beyond their widely reported use as precursors for single-layer graphene sheets, are in fact excellent materials themselves (polymers in two-dimension, polyelectrolyte-like, aqueous solubility and biocompatibility, etc.). In this reported work we used aqueous GOs to effectively disperse few-layer graphene sheets (GNs) in suspension for facile wet-processing into nanocomposites of GNs embedded in GOs (as the polymeric matrix). The resulting lightweight and plastic-like nanocomposite materials remained mechanically flexible even at high loadings of GNs, and they were found to be highly efficient in thermal transport, with the experimentally determined thermal diffusivity competitive to those typically observed only in well-known thermally conductive metals such as aluminum and copper. As demonstrated, GOs apparently represent a unique class of two-dimensional polymeric materials for potentially “all-carbon” nanocomposites, among others, which may find technological applications independent of those widely proclaimed for graphene sheets.