Multiple Twinning As a Structure Directing Mechanism in Layered Rock-Salt-Type Oxides: NaMnO2 Polymorphism, Redox Potentials, and Magnetism

详细信息    查看全文

• 作者：Artem M. Abakumov ; Alexander A. Tsirlin ; Ioanna Bakaimi ; Gustaaf Van Tendeloo ; Alexandros Lappas
• 刊名：Chemistry of Materials
• 出版年：2014
• 出版时间：May 27, 2014
• 年：2014
• 卷：26
• 期：10
• 页码：3306-3315
• 全文大小：670K
• 年卷期：v.26,no.10(May 27, 2014)
• ISSN：1520-5002

文摘

New polymorphs of NaMnO₂ have been observed using transmission electron microscopy and synchrotron X-ray powder diffraction. Coherent twin planes confined to the (NaMnO₂) layers, parallel to the (101虆) crystallographic planes of the monoclinic layered rock-salt-type 伪-NaMnO₂ (O3) structure, form quasi-periodic modulated sequences, with the known 伪- and 尾-NaMnO₂ polymorphs as the two limiting cases. The energy difference between the polymorphic forms, estimated using a DFT-based structure relaxation, is on the scale of the typical thermal energies that results in a high degree of stacking disorder in these compounds. The results unveil the remarkable effect of the twin planes on both the magnetic and electrochemical properties. The polymorphism drives the magnetic ground state from a quasi-1D spin system for the geometrically frustrated 伪-polymorph through a two-leg spin ladder for the intermediate stacking sequence toward a quasi-2D magnet for the 尾-polymorph. A substantial increase of the equilibrium potential for Na deintercalation upon increasing the concentration of the twin planes is calculated, providing a possibility to tune the electrochemical potential of the layered rock-salt ABO₂ cathodes by engineering the materials with a controlled concentration of twins.