CuI-Nanoparticles-Catalyzed Selective Synthesis of Phenols, Anilines, and Thiophenols from Aryl Halides in Aqueous Solution

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• 作者：Hua-Jian Xu ; Yu-Feng Liang ; Zhen-Ya Cai ; Hong-Xia Qi ; Chun-Yan Yang ; Yi-Si Feng
• 刊名：Journal of Organic Chemistry
• 出版年：2011
• 出版时间：April 1, 2011
• 年：2011
• 卷：76
• 期：7
• 页码：2296-2300
• 全文大小：894K
• 年卷期：v.76,no.7(April 1, 2011)
• ISSN：1520-6904

文摘

CuI-nanoparticles-catalyzed selective synthesis of phenols, anilines, and thiophenols from aryl halides was developed in the absence of both ligands and organic solvents. Anilines were formed selectively with ammonia competing with hydroxylation and thiophenols were generated selectively with sulfur powder after subsequent reduction competing with hydroxylation and amination.