Inactivation and Mineralization of Aerosol Deposited Model Pathogenic Microorganisms over TiO2 and Pt/TiO2

详细信息    查看全文

• 作者：E. A. Kozlova ; A. S. Safatov ; S. A. Kiselev ; V. Yu. Marchenko ; A. A. Sergeev ; M. O. Skarnovich ; E. K. Emelyanova ; M. A. Smetannikova ; G. A. Buryak ; A. V. Vorontsov
• 刊名：Environmental Science & Technology
• 出版年：2010
• 出版时间：July 1, 2010
• 年：2010
• 卷：44
• 期：13
• 页码：5121-5126
• 全文大小：208K
• 年卷期：v.44,no.13(July 1, 2010)
• ISSN：1520-5851

文摘

Air disinfection from bacteria and viruses by means of photocatalytic oxidation is investigated with microorganisms loaded over photocatalysts’ films from aerosols. Deposition method and equipment have been developed to load Mycobacterium smegmatis, Bacillus thuringiensis, vaccinia virus, and influenza A (H3N2) virus on slides with undoped TiO₂ and platinized sulfated TiO₂ (Pt/TiO₂). Inactivation dynamics was measured under UVA irradiation and in the dark. About 90% inactivation is reached in 30 min irradiation on TiO₂ and from 90 to 99.8% on Pt/TiO₂. The first-order inactivation rate coefficient ranged from 0.18 to 0.03 min⁻¹, over Pt/TiO₂ being higher than on TiO₂ for all microorganisms except Bacillus thuringiensis. The photocatalytic mineralization of Bacillus thuringiensis was performed on TiO₂ and Pt/TiO₂ with different photocatalyst and microorganism loadings. Completeness of mineralization depended on the TiO₂ to bacteria mass ratio. The rate of the photocatalytic carbon dioxide production grows with both the cell mass increase and the photocatalyst mass increase. Pt/TiO₂ showed increased rate of mineralization as well as of the inactivation likely due to a better charge carrier separation in the doped semiconductor photocatalyst. The results demonstrate that photocatalytic filters with deposited TiO₂ or Pt/TiO₂ are able to inactivate aerosol microorganisms and completely decompose them into inorganic products and Pt/TiO₂ provides higher disinfection and mineralization rates.