tert-Butyl Nitrite: Organic Redox Cocatalyst for Aerobic Aldehyde-Selective Wacker–Tsuji Oxidation

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• 作者：Xiao-Shan Ning ; Mei-Mei Wang ; Chuan-Zhi Yao ; Xian-Min Chen ; Yan-Biao Kang
• 刊名：Organic Letters
• 出版年：2016
• 出版时间：June 3, 2016
• 年：2016
• 卷：18
• 期：11
• 页码：2700-2703
• 全文大小：414K
• 年卷期：0
• ISSN：1523-7052

文摘

An aldehyde-selective aerobic Wacker–Tsuji oxidation is developed. Using tert-butyl nitrite as a simple organic redox cocatalyst instead of copper or silver salts, a variety of aldehydes were achieved as major products in up to 30/1 regioselectivity as well as good to high yields at room temperature.