鈥淵in and Yang鈥?Tuned Fluorescence Sensing Behavior of Branched 1,4-Bis(phenylethynyl)benzene
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- 作者：Xiaohuan Sun ; Yanyu Qi ; Huijing Liu ; Junxia Peng ; Kaiqiang Liu ; Yu Fang
- 刊名：ACS Applied Materials & Interfaces
- 出版年：2014
- 出版时间：November 26, 2014
- 年：2014
- 卷：6
- 期：22
- 页码：20016-20024
- 全文大小：510K
- ISSN：1944-8252
文摘
Achieving high sensing performance and good photostability of fluorescent films based on adlayer construction represents a significant challenge in the area of functional fluorescent film research. A solution may be offered by 鈥淵in and Yang鈥? a balance idea from Chinese philosophy, for the design of a fluorophore and the relevant assembly. Accordingly, a 1,4-bis(phenylethynyl)benzene (BPEB) derivative (C2) with two cholesteryl residues in the side chains and two glucono units in the head and tail positions was designed and synthesized. As a control, compound C1 was also prepared. The only difference between C1 and C2 is that the hydroxyl groups in the glucono residues of C1 are fully acetylated. Studies of the fluorescence behaviors of the two compounds in solution revealed that both the profile and the intensity of the fluorescence emission of the compounds, in particular C2, are dependent on their concentration and on the nature of solvents employed. Presence of HCl also alters the emission of the compounds in solution. On the basis of the studies, three fluorescent films were prepared, and their sensing performances to HCl in vapor state were studied. Specifically, Film 1 and Film 3 were fabricated via physical coating, separately, of C2 and C1 on glass plate surfaces. As another comparison, Film 2 was also fabricated with C2 as a fluorophore but at a much lower concentration if compared to that for the preparation of Film 1. As revealed by SEM and fluorescent microscopy studies, Film 1 and Film 2 exhibit well-defined microstructures, which are spherical particles and spherical pores, respectively, while Film 3 is characterized by irregular aggregates of C1. Fluorescence measurements demonstrated that Film 1 and Film 3 both display an aggregation emission, of which the emission from Film 1 is supersensitive to the presence of HCl vapor (detection limit: 0.4 ppb, a lowest value reported in the literatures). For Film 3, however, its emission is insensitive to the presence of the vapor. Similarly, the emission from the nonaggregated state of C2, a characteristic emission of Film 2, is also insensitive to the presence of the vapor. Furthermore, the sensing process of Film 1 to the vapor is highly selective and fully reversible, which lays foundation for its real-life uses. As for C2, the results from solution studies and those from film studies demonstrate clearly that introduction of auxiliary structures with opposite properties onto a typical fluorophore is a good strategy to develop fluorescent supramolecular motifs with rich assembly properties and great potential of applications.