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Morphological Effects on Surface-Enhanced Raman Scattering from Silver Butterfly Wing Scales Synthesized via Photoreduction
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文摘
Through a simple room-temperature photoreduction process, this letter conformally replicates 3D submicrometer structures of wing scales from two butterfly species into Ag to generate practical surface-enhanced Raman scattering (SERS) substrates. The Ag replicas of butterfly scales with higher structural periodicity are able to detect rhodamine 6G at a low concentration down to 10<sup>鈥?sup> M, which is three orders of magnitude lower than the detectable concentration limit of using quasi-periodic Ag butterfly structures. This result presents a way to select suitable scale morphologies from 174鈥?00 species of Lepidopterans to replicate, as consumable SERS substrates with low cost and high reproducibility.

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