Photodesorption and Photostability of Acetone Ices: Relevance to Solid Phase Astrochemistry

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• 作者：Guilherme C. Almeida ; S茅rgio Pilling ; Diana P. P. Andrade ; Nathany Lisb么a S. Castro ; Edgar Mendoza ; Helo铆sa M. Boechat-Roberty ; Maria Luiza M. Rocco
• 刊名：Journal of Physical Chemistry C
• 出版年：2014
• 出版时间：March 27, 2014
• 年：2014
• 卷：118
• 期：12
• 页码：6193-6200
• 全文大小：378K
• 年卷期：v.118,no.12(March 27, 2014)
• ISSN：1932-7455

文摘

Acetone, one of the most important molecules in organic chemistry, also a precursor of prebiotic species, was found in the interstellar medium associated with star-forming environments. The mechanisms proposed to explain the gas phase abundance of interstellar acetone are based on grain mantle chemistry. High energy photons coming from the stellar radiation field of the nearby stars interact with the ice mantles on dust grains leading to photoionization, photodissociation, and photodesorption processes. In this work we investigate the photodesorption and the photostability of pure acetone ices due to soft X-ray impact. Absolute desorption yields per photon impact for the main positive ionic fragments were determined at the O 1s resonance energy (531.4 eV). The photostability of acetone ice was studied by exposure to different irradiation doses with a white beam of synchrotron radiation. The degradation of the ice was monitored by NEXAFS around the O 1s threshold. From this study we determine the photodissociation cross-section to be about 1.5 脳 10^鈥?7 cm² which allowed us to estimate the half-life for acetone ice in astrophysical environments where soft X-rays play an important role in chemical processes.