文摘
Transparent conductors (TCs) are an important component of optoelectronic devices and nanoscale engineering of TCs is important for optimization of the device performance through improved light trapping. In this work, patterned periodic arrays of nanopillars and nanolines of pitch size of 700 nm were created on fluorine-doped tin oxide (FTO) using nanoimprint lithography and reactive ion etching using environmentally friendly gases. The patterned FTO exhibits enhanced light trapping as compared to the unpatterned FTO, which agrees well with simulations based on Finite-Difference Time-Domain method for up to a distance of 4 渭m. Dye sensitized solar cells (DSSCs) fabricated on the patterned FTO exhibited improved performance (fill factor and power conversion efficiency), which can be attributed to enhanced light absorption in the range 400鈥?50 nm. Further, electrochemical impedance measurements revealed lower recombination resistance for the patterned FTO/TiO2 electrode compared to the unpatterned FTO electrode/TiO2 electrode as a result of better light capturing properties of patterned FTO. The direct fabrication of nanopatterns on TCs developed in the present study is expected to be a viable scheme for achieving improved performance in many other optoelectronic devices.
Keywords:
photovoltaic; nanopatterned transparent conductors; light scattering; nanoimprint lithography; dye sensitized solar cells; fluorine-doped tin oxide