Coordination Polymers Based on the Trinuclear Triangular Secondary Building Unit [Cu3(渭3-OH)(渭-pz)3]2+ (pz = pyrazolate) and Succinate Anion

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• 作者：Corrado Di Nicola ; Enrico Forlin ; Federica Garau ; Massimo Gazzano ; Arianna Lanza ; Magda Monari ; Fabrizio Nestola ; Luciano Pandolfo ; Claudio Pettinari ; Alberto Zorzi ; Federico Zorzi
• 刊名：Crystal Growth & Design
• 出版年：2013
• 出版时间：January 2, 2013
• 年：2013
• 卷：13
• 期：1
• 页码：126-135
• 全文大小：530K
• 年卷期：v.13,no.1(January 2, 2013)
• ISSN：1528-7505

文摘

Reaction conditions (solvent, temperature, pressure) and reagents ratios control the formation of different products from the reactions involving Cu^II, pyrazole (Hpz), and succinate ion (Suc). Three different coordination polymers (CPs) (one of which porous) based on the trinuclear triangular Cu₃(渭₃-OH)(渭-pz)₃ secondary building unit (SBU), as well as a 1D CP based on the Cu(Hpz)₂ SBU were obtained. Moreover, a 3D supramolecular network, formed through quite strong H-bonding interactions involving the mononuclear Cu(HSuc)₂(Hpz)₄ complex, was also synthesized when an excess of H₂Suc was added.