Photocatalytic Decarboxylative Hydroxylation of Carboxylic Acids Driven by Visible Light and Using Molecular Oxygen

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• 作者：Hai-Tao Song ; Wei Ding ; Quan-Quan Zhou ; Jing Liu ; Liang-Qiu Lu ; Wen-Jing Xiao
• 刊名：Journal of Organic Chemistry
• 出版年：2016
• 出版时间：August 19, 2016
• 年：2016
• 卷：81
• 期：16
• 页码：7250-7255
• 全文大小：477K
• 年卷期：0
• ISSN：1520-6904

文摘

This paper discloses the first example of photocatalytic direct decarboxylative hydroxylation of carboxylic acids. It enables the conversion of a variety of readily available carboxylic acids to alcohols in moderate to high yields. This unprecedented protocol is accomplished under extremely mild reaction conditions using molecular oxygen (O₂) as a green oxidant and using visible light as a driving force.