[Ph3PCH2Ph]2[Zn3(tp)3Cl2] and Ni3(tma)2(H2O)8: Two Unusual Claylike Frameworks of Metal-Po

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• 作者：Guo-Dong Yang ; Jing-Cao Dai ; Yun-Xia Lian ; Wen-Shi Wu ; Jian-Ming Lin ; Sheng-Min Hu ; Tian-Lu Sheng ; Zhi-Yong Fu ; Xin-Tao Wu
• 刊名：Inorganic Chemistry
• 出版年：2007
• 出版时间：September 17, 2007
• 年：2007
• 卷：46
• 期：19
• 页码：7910 - 7916
• 全文大小：480K
• 年卷期：v.46,no.19(September 17, 2007)
• ISSN：1520-510X

文摘

Two new compounds, [Ph₃PCH₂Ph]₂[Zn₃(tp)₃Cl₂] (1) and Ni₃(tma)₂(H₂O)₈ (2) (tp = terephthalate, tma = trimesate),are metal-polycarboxylate coordination polymers prepared by similar hydrothermal synthesis techniques. X-raysingle-crystal structural analysis shows that both compounds crystallize in the 2D claylike lamellar architectures, inwhich 1 possesses the interlayer [Ph₃PCH₂Ph]⁺ exchangeable cation and has been confirmed by PXRD patterns.1 (C₇₄H₅₆Cl₂O₁₂P₂Zn₃) belongs to monoclinic P2₁/c, Z = 2 (a = 18.956(1) Å, b = 10.2697(5) Å, c = 17.067(1) Å, = 99.486(4)). 2 (C₁₈H₂₂O₂₀Ni₃) is attributed to triclinic P, Z = 1 (a = 6.6643(8) Å, b = 9.622(1) Å, c =10.089(1) Å, = 112.675(2), = 94.007(1), = 106.411(2)). Linear metal trinuclear clusters bridged by rigidlinear tp ligands for 1 and trigonal tma ligands for 2 give rise to a novel 2D 6-linked (3,6) topological anionicnetwork in 1 and an interesting 2D 3,6-linked molybdenite topological neutral network in 2, respectively. Bothcompounds exhibit intense fluorescent emission bands at 410 nm (_exc = 355 nm) for 1 and 398 nm (_exc = 300nm) for 2 in the solid state at room temperature.