Pentamethylcyclopentadienyltitanium aryl(pyridyl)amide complexes: Synthesis, characterization and catalytic performance for olefin polymerization
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- 作者：Qiang Zhang ; Xin Tao ; Wei Gao ; Tingting Song ; Ying Mu ; ymu@jlu.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Atactic polypropylene ; Half-titanocene complexes ; Olefin polymerization ; Polyethylene
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：15 February 2016
- 年：2016
- 卷：804
- 期：Complete
- 页码：18-25
- 全文大小：873 K
文摘
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New cyclopentadienyl titanium (IV) aryl(pyridyl)amide complexes were synthesized.
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High catalytic activities for ethylene and propylene polymerization were observed.
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High molecular weight polyethylene and atactic polypropylene were produced.