Synthesis, NMR analysis and X-ray crystal structure of 3-(2-naphthoyl)-6,12-diphenyl-3,9-diazatetraasterane

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• 作者：Hong-bo Tan^a ; Xiu-qing Song^a ; Hong Yan^a ; ^{hongyan@bjut.edu.cn} ; Hong-xing Xin^b
• 关键词：3 ; 9-Diazatetraasterane ; Synthesis ; NMR analysis ; Spatial effects ; X-ray crystal structure
• 刊名：Journal of Molecular Structure
• 出版年：2017
• 出版时间：5 February 2017
• 年：2017
• 卷：1129
• 期：Complete
• 页码：23-31
• 全文大小：1632 K
• 卷排序：1129

文摘

Novel 3,9-diazatetraasterane (3) was synthesized and characterized by NMR and XRD. 1D-NMR and 2D-NMR of 3 were conducted in details to discuss the spatial effects. Single-crystal X-ray diffraction assists to explain the molecular asymmetry of 3. Single-crystal X-ray diffraction elucidates the distortion of the central cage of 3.