Radical polymerization behavior and thermal properties of vinyl ethylene carbonate derivatives bearing aromatic moieties
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- 作者：Yoshiaki Yoshida ; Takeshi Endo ; tendo@moleng.fuk.kindai.ac.jp" class="auth_mail" title="E-mail the corresponding author
- 关键词：Radical polymerization ; Vinyl ethylene carbonate ; Selective vinyl polymerization ; Chain transfer reaction ; Bifunctional polymer
- 刊名：Polymer
- 出版年：2016
- 出版时间：12 October 2016
- 年：2016
- 卷：102
- 期：Complete
- 页码：167-175
- 全文大小：2341 K
文摘
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Radical polymerization of the VEC derivatives bearing aromatic moieties proceeded through the selective vinyl fashion.
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Chain transfer reaction occurred readily toward the solvents and the moieties were inserted into the chain-end.
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Radical polymerization of the bifunctional monomer proceeded through the same mechanism with the monofunctional monomers.
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The cross-linked polymer exhibited high thermal stability than the monofunctional VEC polymers.