The Co(II), Ni(II) and Cu(II) complexes with herbicide 2,4-dichlorophenoxyacetic acid - Synthesis and structural studies

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• 作者：Aleksandra Drzewiecka-Antonik^a ; ^{adrzew@ifpan.edu.pl} ; Wiesława Ferenc^b ; Anna Wolska^a ; Marcin T. Klepka^a ; Beata Crist&oacute ; vã ; o^b ; Jan Sarzyński^c ; Paweł Rejmak^a ; Dariusz Osypiuk^b
• 关键词：Transition metal complexes ; 2 ; 4-Dichlorophenoxyacetic acid ; IR spectroscopy ; Magnetic properties ; XAFS studies ; DFT calculations
• 刊名：Chemical Physics Letters
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：667
• 期：Complete
• 页码：192-198
• 全文大小：1490 K
• 卷排序：667

文摘

Three mononuclear complexes with herbicide-2,4-D were structurally investigated. Metal–ligand interactions were studied by XAS and DFT. Monodentate coordination by carboxylate ligands was found for powder samples. Dinuclear ‘Chinese lantern’ structure was found for crystallized Ni(II) complex.