Ruthenium(II) bipyridine complexes with pendant anthracenyl and naphthyl moieties: A strategy for a ROS generator with DNA binding selectivity
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- 作者：Felipe Dió ; genes Abreu ; Izaura Cirino Nogueira Dió ; genes ; Luiz Gonzaga de Franç ; a Lopes ; Eduardo Henrique Silva Sousa ; eduardohss@dqoi.ufc.br" class="auth_mail" title="E-mail the corresponding author ; Idalina Maria Moreira de Carvalho ; idalina@dqoi.ufc.br" class="auth_mail" title="E-mail the corresponding author
- 关键词：ROS generators ; Singlet oxygen ; Ruthenium bipyridine
- 刊名：Inorganica Chimica Acta
- 出版年：2016
- 出版时间：1 January 2016
- 年：2016
- 卷：439
- 期：Complete
- 页码：92-99
- 全文大小：1447 K
文摘
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Anthracenyl and naphthyl-bipyridine coordinated to ruthenium(II) show ROS photogeneration.
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Ruthenium(II) anthracenyl bipyridine showed production of both singlet oxygen and hydroxyl radical.
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Anthracenyl-bipyridine moiety promoted binding to DNA while enhanced efficient photocleavage under visible light.
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Potential application as a tool in cellular biology (CALI) and therapy.
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