Cu1+xMn1−xAs single crystals can be grown using bismuth flux.
Crystal structure of CuMn3As2 and Cu2Mn4As3 refined from single crystal x-ray diffraction data.
The orthorhombic unit cell of CuMn3As2 and Cu2Mn4As3 twice as large compared to CuMnAs.
Cu2Mn4As3 is a new compound with magnetic order below 300 K and semi-metallic behavior.