Influence of LiAl-layered double hydroxides with 3D micro-nano structures on the properties of calcium sulphoaluminate cement clinker

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• 作者：Xuemao Guan ; Haiyan Li ; ^{lihaiyan@hpu.edu.cn" class="auth_mail" title="E-mail the corresponding author} ; Shuqiong Luo ; Xiaoxing Liu ; Jianwu Zhang
• 关键词：LiAl-layered double hydroxides ; Calcium sulphoaluminate cement clinker ; Particle size ; Content
• 刊名：Cement and Concrete Composites
• 出版年：2016
• 出版时间：July 2016
• 年：2016
• 卷：70
• 期：Complete
• 页码：15-23
• 全文大小：1817 K

文摘

The effect of LiAl-layered double hydroxides (LiAl-LDHs) with 3D micro-nano structures on the early properties and hydration process of calcium sulphoaluminate cement (CSAC) clinker was investigated. Three LiAl layered double hydroxides (LiAl-LDHs) with different particle size were prepared through a facile solvothermal method. CSAC clinker incorporating LiAl-LDHs with constant water to cement radio were made and tested. The results indicate that a higher content of LiAl-LDHs resulted in a faster hydration rate, a shorter setting time and a higher early compressive strength. Besides, with the decrease of the particle size of LiAl-LDHs, the hydration rate was accelerated with corresponding increase in compressive strength. However, the influence of particle size of LiAl-LDHs on the setting time of CSAC clinker is not significant. Moreover, the addition of LiAl-LDHs did not result in a new phase formed, but increased the quantity of hydration products providing higher compressive strength and shorter setting time.