Synthesis, characterization and catalytic activity under homogeneous conditions of ethylene glycol substituted porphyrin manganese(III) complexes

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• 作者：Kelly A.D.F. Castro^a ; ^b ; Fernando H.C. de Lima^a ; Má ; rio M.Q. Simõ ; es^b ; ^{msimoes@ua.pt} ; M. Graç ; a P.M.S. Neves^b ; Filipe A. Almeida Paz^c ; Ricardo F. Mendes^c ; Shirley Nakagaki^a ; ^{shirleyn@ufpr.br} ; José ; A.S. Cavaleiro^b
• 关键词：Porphyrins ; Ethylene glycol ; Manganese ; Oxidation ; Hydrogen peroxide
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：30 January 2017
• 年：2017
• 卷：455
• 期：part_P2
• 页码：575-583
• 全文大小：1735 K
• 卷排序：455

文摘

Synthesis and characterization of ethylene glycol substituted Mn(III) porphyrins. Catalysis with ethylene glycol substituted Mn(III) porphyrins at ambient temperature. Oxidation of cis-cyclooctene and cyclohexane in the presence of hydrogen peroxide. Catalysts’ performance depends on the number of ethylene glycol moieties present. Tetrasubstituted free-base porphyrin is studied by single-crystal X-ray diffraction.