Synthesis of hydroxymethylfurfural from cellulose using green processes: A promising biochemical and biofuel feedstock

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• 作者：Prasant Kumar Rout^a ; ^c ; ^{pk.rout@cimap.res.in" class="auth_mail" title="E-mail the corresponding author} ; Ashween Deepak Nannaware^a ; ^c ; Om Prakash^a ; ^c ; Alok Kalra^b ; ^c ; Ram Rajasekharan^c ; ^d
• 关键词：Lignocellulosic biomass ; Cellulose ; 5-hydroxymethylfurfural ; Bio-fuel ; Bio-chemical ; Levulinic acid
• 刊名：Chemical Engineering Science
• 出版年：2016
• 出版时间：13 March 2016
• 年：2016
• 卷：142
• 期：Complete
• 页码：318-346
• 全文大小：5193 K

文摘

Inedible, lignocellulosic biomass has been recognized as most promising renewable resource for the production of high value bio-chemicals. The pretreated biomass or isolated cellulose is a biopolymer of glucose used as a stating material for the synthesis of 5-hydroxymethylfurfural (HMF). HMF is listed among the top 10 bio-based chemicals by USA Department of Energy and it acts as feedstock for deriving a number of commodity products (Bonzell and Petersen, 2010, Green Chem. 12, 539). In present review, we have systematically summarized the catalytic reaction for the synthesis of HMF from pretreated biomass/isolated cellulose using green processes. Further, through catalytic approach, HMF is translated into industrial important chemicals (2,5-diformylfuran, furan-2,5-dicarboxylicacid, 2,5-furandimethanol, furfuraylalcohol, etc) or high calorific value biofuel (2,5-dimethylfuran, 2,5-dimethyltetrahydrofuran, 2,5-bis(alkoxymethyl)furans, etc). In the profitable scale of HMF production, levulinic acid (LA) is generated as a major byproduct. Besides HMF, this review also outlines the catalytic strategy for the conversion of LA to industrially important chemicals along with the biofuel additives. Finally, the bio-toxicity of synthesized chemicals, which connected into different functional groups have been summarized to meet the criteria of the green technology for commercialization.