Niobium oxides: Correlation of acidity with structure and catalytic performance in sucrose conversion to 5-hydroxymethylfurfural
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- 作者：Hannah Theresa Kreissla ; Keizo Nakagawaa ; b ; Yung-Kang Penga ; Yusuke Koitoa ; Junlin Zhengc ; Shik Chi Edman Tsanga ; edman.tsang@chem.ox.ac.uk" class="auth_mail" title="E-mail the corresponding author
- 关键词：Niobium oxide ; Lewis/Brø ; nsted acidity ; Structure&ndash ; acidity relation ; Sugar conversion ; Green chemistry
- 刊名：Journal of Catalysis
- 出版年：2016
- 出版时间：June 2016
- 年：2016
- 卷：338
- 期：Complete
- 页码：329-339
- 全文大小：2493 K
文摘
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Niobium oxides with varying acidities are compared systematically.
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Acidity-activity relations established for the catalytic conversion of sugars to HMF.
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New reaction mechanistic details of sucrose, glucose and fructose conversion to HMF.
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New insights into structure-acidity relations.
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Conversion of relatively cheap sucrose to HMF of interest for renewable energy sector.