Observation of the epitaxial growth of the MoS2 film on the GaN/AlGaN/GaN (0001) substrate and c-axis oriented nanocrystalline MoS2 film on the Si (100) substrate. Dependence of the Raman peak position on the crystal structure of MoS2 film. Non-linear thickness dependence on the number of laser pulses using PLD from the stoichiometric target.