Facilitated Ion Transport in Smectic Ordered Ionic Liquid Crystals
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- 作者：Jin Hong Lee ; Kee Sung Han ; Je Seung Lee ; Albert S. Lee ; Seo Kyung Park ; Sung Yun Hong ; Jong-Chan Lee ; Karl T. Mueller ; Soon Man Hong and Chong Min Koo
- 刊名：Advanced Materials
- 出版年：2016
- 出版时间：November 9, 2016
- 年：2016
- 卷：28
- 期：42
- 页码：9301-9307
- 全文大小：1246K
- ISSN：1521-4095
文摘
A novel ionic mixture of an imidazolium-based room-temperature ionic liquid containing ethylene-oxide-functionalized phosphite anions is fabricated, which, when doped with lithium salt, self-assembles into a smectic-ordered ionic liquid crystal through Coulombic interactions between the ion species. Interestingly, the smectic order in the ionic-liquid-crystal ionogel facilitates ionic transport.