泰国甲仑榴莲的果肉及内果皮挥发油成分的GC-MS分析
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摘要
目的:分析甲仑榴莲挥发油成分,为开发利用榴莲资源和质量控制提供科学依据.方法:采用水蒸气蒸馏法提取榴莲果肉及内果皮中的挥发油,采用GC-MS法和NIST98谱图库鉴定化学成分.结果:从榴莲果肉中鉴定出11种化合物,其含量占挥发油总含量的98.86%,其主要成分及相对含量分别为环十六烷(43.59%),9-十六碳烯酸乙酯(11.17%),十六烷(10.59%),棕榈酸乙酯(9.12%),以烷类和酯类化合物为主;从榴莲内果皮中鉴定出11种化合物,占总挥发油含量的95.73%,其主要成分及相对含量分别为十六烷(25.71%),2-十四烯(E)(22.41%),9-十六碳烯酸乙酯(13.56%),苯乙烯(13.45%),以烷类和烯烃类为主.结论:为榴莲挥发油的进一步研究及开发利用提供科学依据.
Objective: To analyze the constituents of the essential oils extracted from Jia Lun durian,and provide scientific basis for quality control of it. Methods: The essential oils were extracted from durian pulp and peel by water steam distillation. The components were identified by GC-M S and NIST data base. Results: 11 compounds from durian pulp were identified and accounted for 98. 86% of all essential oil. The main components were hexadecane( 43. 59%),ethyl 9-hexadecenoate( 11. 17%),hexadecane( 10. 59%),palmitic acid ethyl ester( 9. 12%).Alkanes and esters were the main components. In durian peel,the 11 kinds of compounds wereidentified and accounted for 95. 73% of the total volatile oil,in which was mainly hexadecane( 25. 71%),2-tetradecene( E)( 22. 41%),ethyl 9-hexadecenoate( 13. 56%),styrene( 13. 45%).Alkanes and alkene were the main components. Conclusion: The study provided a scientific basis for the development and utilization of volatile oils from durian.
Objective: To analyze the constituents of the essential oils extracted from Jia Lun durian,and provide scientific basis for quality control of it. Methods: The essential oils were extracted from durian pulp and peel by water steam distillation. The components were identified by GC-M S and NIST data base. Results: 11 compounds from durian pulp were identified and accounted for 98. 86% of all essential oil. The main components were hexadecane( 43. 59%),ethyl 9-hexadecenoate( 11. 17%),hexadecane( 10. 59%),palmitic acid ethyl ester( 9. 12%).Alkanes and esters were the main components. In durian peel,the 11 kinds of compounds wereidentified and accounted for 95. 73% of the total volatile oil,in which was mainly hexadecane( 25. 71%),2-tetradecene( E)( 22. 41%),ethyl 9-hexadecenoate( 13. 56%),styrene( 13. 45%).Alkanes and alkene were the main components. Conclusion: The study provided a scientific basis for the development and utilization of volatile oils from durian.
引文
[1]Subhadrabandhu S,Ketsa S,Daphne T,et al.Durian,king of tropical fruit[M].New Zealand:New Zealand publishing company,2001:178-178.[2]孙俊秀.水果中的臭豆腐——榴莲[J].四川烹饪高等专科学校学报,2004(4):18-19.[3]杨敬勇,孟鸿菊.榴莲与人体健康研究进展[J].中国果业信息,2007,24(1):29-30.[4]宫佳,付娜.水果之王——榴莲[J].中国学术期刊电子杂志社,2015:18-19.[5]高婷婷,刘玉平,孙宝国.SPME-GC-MS分析榴莲果肉中的挥发性成分[J].精细化工,2014,31(10):1230-1234.[6]刘倩,黄文艺.榴莲中香气成分分析[J].分析测试学,1999,18(2):58-60.[7]张博,李书倩,辛广,等.金枕榴莲果实各部位挥发性物质成分GC/MS分析[J].食品研究与开发,2012,33(1):130-134.[8]Li J X,Schieberle P,Steinhaus M.Characterization of the major odor-active compounds in Thai durian(Durio zibethinus L.'M onthong')by aroma extract dilution analysis and headspace gas chromatography-olfactometry[J].Journal of Agricultural and Food Chemistry,2012,60(45):11253-11262.[9]张弘,郑华,冯颖,等.金枕榴莲果实挥发性成分的热脱附-气相色谱/质谱分析[J].食品科学,2008,29(10):517-519.[10]张继,刘阿萍,姚健,等.榴莲果皮挥发性化学成分的分析[J].食品科学,2003,24(6):128-131.[11]Zhang Z M,Zeng D D,Li G K.The study of the aroma profile characteristics of durian pulp during storage by the combination sampling method coupled w ith GC-M S[J].Flavour and Fragrance Journal,2007,22(1):71-77.[12]Chin S T,Nazimah S A H,Quek S Y,et al.Analysis of volatile compounds from Malaysian durians(Durio zibethinus)using headspace SPM E coupled to fast GC-M S[J].Journal of Food.Composition and Analysis,2007,20(1):31-44.[13]中国药典,一部[S].2010:附录XD:63.[14]刘玉峰,李胜男,朱美霞,等.苏木挥发油成分的GC-MS分析[J].辽宁大学学报:自然科学版,2016,43(2):175-178.