The Pusangguo copper-polymetallic deposit is located in Nanmulin volcanic basin. Petrographic and geochemical studies of granodiorite, granodiorite-porphyry and diorite-porphyrite show that the intrusive rocks are of calc-alkaline series, with ω(SiO3) ranging from 59.08% to 67.28%, ω(Al2O3) ranging from 15.38% to 16.86% ω(MgO) ranging from 1.52% to 4.06%, and co(TFeO) ranging from 1.2% to 3.46%. Petrographic and geochemical studies indicate that granodiorite-porphyry and diorite-porphyrite were produced by Tethys subduction towards