摘要
The Shedong tungsten and molybdenum deposit in Cangwu County,Guangxi is a quartz-skarn type deposit related to granitoids.Major granitoids are comprised of Caledonian granodiorite,granodiorite-porphyry and Late Yanshanian granite porphyry in mineral district.Caledonian granodiorite and granodiorite-porphyry dominantly exhibit low Si,K,high Na,Al and basic components, thus can be classified to the normal calc-alkaline granite with strongly peraluminous.The rocks are characterized by low REE contents, high LREE/HREE ratios,weakly Eu depletion(δEu=0.62~0.70),depletion of Ti,Nb,Ta,enrichment of Th,U,Pb,Zr,Hf, low Rb/Sr ratio(0.78),obviously enrichment of W,Mo,Cu.Geochemical evidences indicate that early Caledonian granodiorite (-porphyry)are I-type granite,and formed in compression tectonic setting of early collision stage in intra-continent orogenic belt,and associated with W,Mo,Cu mineralization.Late Yanshanian granite porphyry dominantly exhibit high Si,K,low Na,Ca and basic contents,can be defined as the high-moderate potassium calc-alkaline granite with strong peraluminous.The rock is characterized by relative high REE contents,low LREE/HREE ratios,strong Eu depletion(δEu=0.03~0.06),depletion of Ti,Ba,K,Eu,more enrichment of Th,U,Sm,Dy,Y,Ho,Yb,Lu,high Rb/Sr ratio(7.56),clearly enrichment of Sn,Bi,thus it is assigned to Late Yanshanian S-type granite evolved well,and formed in intraplate extension tectonic setting of post-collision,and is related to Sn,Au mineralization.