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Organogenic Dolomitization within the Middle Permian Siliceous-Rock Set in Maokou Formation of Sangzhi, Hunan Province
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摘要


     The Rencunping RCP section in Sangzhi of Hunan Province is a typical location developing a set of organic-rich siliceous deposits in the middle part of Maokou Formation, significantly, which is intermitted with several dolomite beds. Micromorphologic features of dolomitic crystallites present poorly-ordered and aphanitic textures in the form of anhedral clusters, which is distinctly different from the rhomboidal textures formed in diagenesis. These features might evidently indicate that organogenic dolomitization occurred in the environment of oxidation of burial organic matters by bacterial sulfate reduction in sedimentary pore water. In addition, negative relationship of δ^13C vs. δ^180 values has been detected in the entire siliceous-rock interval. We infer that should be the results also from the enhanced influences of SRB processes of burial organic matters. The occurrence with relatively high δ^18O values in the bioclastic dolomites might track the O-isotopic compositions back in the shallow-water environments indicating unique fractionating pathway on degradations of organic matters after reworking. The abnormalities with relatively low δ^13 C values occurred distinctively in the dolomite beds at sampling positions of 4. 5m and 5.9m, which should mark the dominance of anoxic oxidation of methane AOM releasing from the underlying layers. Due to poor conditions in terms of porosities and availabilities of precipitated carbonates in the rocks of marls and calcareous mudstone, inwhere it prevented the activities of SRB to form the organogenic dolomite, alternatively, to be replaced by methanogensis in deep burial depth to derive^ 13 C-enriched DIC in alkaline pore fluids. Therefore, the consistent evidence mentioned above inferred that the depositional environment of the siliceous-rock set in Rencunping section was preferably in the slope facies in cases of enhanced supplies and deposits of organic matters.

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